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AFAIK the answer to both is No.

As far as I know, the frame number padding can only be configured from the command line:

From the wiki:

 -o or --render-output <path>
     Set the render path and file name.
     Use // at the start of the path to
         render relative to the blend file.
     The # characters are replaced by the frame number, and used to define zero padding.
         ani_##_test.png becomes ani_01_test.png
         test-######.png becomes test-000001.png
         When the filename does not contain #, The suffix #### is added to the filename
     The frame number will be added at the end of the filename.
         eg: blender -b foobar.blend -o //render_ -F PNG -x 1 -a
         //render_ becomes //render_####, writing frames as //render_0001.png//