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You can get this with a wireframe material using this method (see this):

1. Disable anti-aliasing in render settings

4. Create a material wire material, enable transparency and increase the Z offset:

4. Create another material for your object and make it pure black:

0. Assign the second (black) material to all the faces (Tab> edit mode A> select all > Assign.

1. Set the world color to black:

5. Render:

Note that sometimes with low resolution renders you may have to increase the Z offset even more to prevent gaps in the edges.

You can get this with a wireframe material using this method (see this):

1. Disable anti-aliasing in render settings

   

2. Create a material wire material, enable transparency and increase the Z offset:

   

3. Create another material for your object and make it pure black:

   

4. Assign the second (black) material to all the faces (Tab> edit mode A> select all > Assign.

5. Set the world color to black:

   

6. Render:

   

Note that sometimes with low resolution renders you may have to increase the Z offset even more to prevent gaps in the edges.

You can get this with a wireframe material using this method (see this):

1. Disable anti-aliasing in render settings

4. Create a material wire material, enable transparency and increase the Z offset:

4. Create another material for your object and make it pure black:

0. Assign the second (black) material to all the faces (Tab> edit mode A> select all > Assign.

1. Set the world color to black:

5. Render:

Note that sometimes with low resolution renders you may have to increase the Z offset even more to prevent gaps in the edges.

You can get this with a wireframe material using this method (see this):

1. Disable anti-aliasing in render settings

4. Create a material wire material, enable transparency and increase the Z offset:

4. Create another material for your object and make it pure black:

0. Assign the second (black) material to all the faces (Tab> edit mode A> select all > Assign.

1. Set the world color to black:

5. Render:

Note that sometimes with low resolution renders you may have to increase the Z offset even more to prevent gaps in the edges.

You can get this with freestyle as you suggested:

1. Disable anti-aliasing in render settings

2. Enable freestyle in render settings

3. Set edge mark under freestyle settings in layers and set the line color to what you want:

4. Mark edges on your mesh, by going into edit mode and pressing CtrlE and selecting Mark freestyle edge

4. Create a material for your object and make it pure black:

5. Set the world color to black:

5. Render:

You can get this with a wireframe material using this method (see this):

1. Disable anti-aliasing in render settings

4. Create a material wire material, enable transparency and increase the Z offset:

4. Create another material for your object and make it pure black:

0. Assign the second (black) material to all the faces (Tab> edit mode A> select all > Assign.

1. Set the world color to black:

5. Render:

Note that sometimes with low resolution renders you may have to increase the Z offset even more to prevent gaps in the edges.