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When designing new workspaces, there doesn't seem to be a way to save or define the default mode of that workspace. You can duplicate one of the presets and go from there, which would work fine... but there isn't a preset for painting Vertices, even though this is one of the selectable modes.
Currently it would seem to be impossible to create a vertex painting workspace.
Is there a way to do this?
Either from the 3D View Sidebar > Tools tab or from the Properties Window > Active Tool tab there is a workspace panel.
The dropdown menu allows you to define a default workspace mode. After that save the startup file from the File > Defaults > Save Startup File menu entry so it is available next time you start a new session.
